KMID : 1059519920360030383
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Journal of the Korean Chemical Society 1992 Volume.36 No. 3 p.383 ~ p.392
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Nitrate Ion-Selective Membrane Electrode Based on Complex of (Bakelite-A)-(2,2'-Bipyridine)-Ni(¥±) Nitrate
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Shin Doo-Soon
Chung Ki-Won
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Abstract
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(Bakelite-A)-(2,2'-Bipyridine)-Ni(¥±) Nitrate complexes were tested as ion exchanger for nitrate ion-selective electrode. The experimentally observed selectivity and electrode characteristics were relatively in good agreement with the exchanger lipophilicity in the membrane phase. Based on chemical composition, mechanisms for exchange with nitrate ion and internal electrical conduction were postulated. Analytical application to the determination of nitrate were studied.
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